$$a^2+b^2\ \ \ \ \ \ \ \ \ \ \ \ \ =1\tag{1}$$
$$b^2+c^2+\sqrt{3}bc=1\tag{2}$$
$$c^2+a^2+\ \ \ \ \ ca=1\tag{3}$$
Solution: If $c=0$, based on equation $(2)$ and $(3)$, we have $a^2=1$ and $b^2=1$. Therefore, $a^2+b^2=2$, which is in conflict with equation $(1)$. Therefore $c\ne 0$.
Because $c\ne 0$, based on equation $(1)$ and $(3)$, we have:
$$a=\dfrac{b^2-c^2}{c}\tag{4}$$
Based on equation $(1)$ and $(2)$, we have:
$$a^2=c^2+\sqrt{3}bc\tag{5}$$
Replacing $a$ in equation $(5)$ with equation $(3)$, we have:
$$\Big(\dfrac{b^2-c^2}{c}\Big)^2=c^2+\sqrt{3}bc\tag{6}$$
Simpifying equation $(6)$, we have: $$b(b^3-2bc^2-\sqrt{3}c^3)=0\tag{7}$$
If $b=0$, we have $a^2=1$, $c^2=1$, $c^2+a^2+ca=1$, which leads solutions of $(a, b, c)$ as $(-1, 0, 1)$ and $(1, 0, -1)$.
If $(b^3-2bc^2-\sqrt{3}c^3=0$, as $c\ne 0$, we have: $$\Big(\dfrac{b}{c}\Big)^3-2\Big(\dfrac{b}{c}\Big)-\sqrt{3}=0\tag{8}$$
The rational solution for $\dfrac{b}{c}$ in equation $(8)$ is $\sqrt{3}$. Therefore $$b=\sqrt{3}c$$
Applying the above result in equation $(2)$, we have $$c=\pm\dfrac{\sqrt{7}}{7}$$
which also results in $$b=\pm\dfrac{\sqrt{21}}{7}$$ and $$a=\pm\dfrac{2\sqrt{7}}{7}$$
Combining the all cases, there are 4 real solutions for $(a, b, c)$:
$(-1,0,1)$, $(1,0,-1)$, $\Big(\dfrac{2\sqrt{7}}{7},\dfrac{\sqrt{21}}{7},\dfrac{\sqrt{7}}{7}\Big)$, and $\Big(-\dfrac{2\sqrt{7}}{7},-\dfrac{\sqrt{21}}{7},-\dfrac{\sqrt{7}}{7}\Big)$